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Specifications Synonyms: TMSCl; TMCS; Trimethylchlorosilane; Trimethylsilyl chlorideCAS Number: 75-77-4Formula: C3H9ClSiFormula Weight: 108.64Linear Formula: (CH3)3SiClMDL No.: MFCD00000502Purity: >=99%Boiling Point: 57 C(lit.)Melting Point: -40 C (lit.)Density: 0.856 g/mL at 25 C(lit.)Refractive Index: n20/D 1.387(lit.)Beilstein Registry Number: 1209232EC Number: 200-900-5UNSPSC Code: 12352302General description: Chlorotrimethylsilane is a chloroorganosilane compound mainly used for silylation reactions.Application: Used in Fisher GlycosylationApplication: Chlorotrimethylsilane may be used to synthesize sodium trimethylsilanethiolate (Me3SiSNa) by reacting with sodium sulfide. This protocol is an odorless alternative to the conventional method of synthesizing Me3SiSNa from foul-smelling bis(trimethylsilyl)sulfide and sodium methoxide.Some of its other applications include:. Trapping agent for the anions generated during acyloin condensation.. As a better alternative to the toxic mercuric chloride, for the activation of samarium(Sm) in the Sm-promoted cyclopropanation of both allylic and α-allenic alcohols.. Catalyze the trans-esterification of triglycerides with alcohols to form fatty acid alkyl esters.. Along with lithium bromide, for the conversion of alcohols to the corresponding bromidesRTECS: VV2710000RIDADR: UN1298 - class 3 - PG 2 - TrimethylchlorosilaneWGK Germany: 1Flash Point(F): -4 FFlash Point(C): -20 CR Codes: 11-14-20/21/22-35-37S Codes: 7/9-16-26-36/37/39-45IOD Codes: F,CSymbol: GHS02, GHS05, GHS06Signal Word: DangerHazard Statements: H225-H301 H331-H312-H315-H318Precautionary statements: P210-P280-P301 P310 P330-P305 P351 P338 P310-P370 P378-P403 P233
