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TETRAHYDROFURAN ANHYDROUS 18L UN 2056 3/PG 2, Each

3,015.84

Details

Specifications Tetrahydrofuran (THF) is a saturated cyclic ether mainly used as an organic solvent. On long term storage it forms organic peroxides. This process can be suppressed by adding butylated hydroxytoluene (BHT) as a stabilizer. BHT removes the free radicals required for the peroxide formation. It constitutes the key fragment of various natural products (polyether antibiotics). THF forms double hydrate with hydrogen sulfide, crystal structure of this double hydrate has been investigated by three-dimensional single-crystal studies.Synonyms: THF; Butylene oxide; Oxolane; Tetramethylene oxideMolecular Formula: C4H8OMolecular Weight: 72.11Linear Structural Formula: C4H8OMDL Number: MFCD00005356Purity: >=99.9%Melting Point: -108 C (lit.)Density: 0.889 g/mL at 25 C (lit.)Refractive Index: n20/D 1.407 (lit.)Application: Dry tetrahydrofuran (THF) has been used in the synthesis of dichloro{bis[1,1′,1′′-(phosphinetriyl)tripiperidine]}palladium [(P(NC5H10)3)2Pd(Cl)2], which is widely used in the Heck reaction as a catalyst. It has been employed in the reaction medium of the Heck cross-coupling reaction of various aryl bromides and olefins.Other Notes: Greener alternatives are available for many THF applications, 2-Methyltetrahydrofuran (414247) and Cyclopentyl methyl ether (675970)Assay: ≥99.9%Autoignition Temp.: 610°FBP: 65-67°C(lit.)Contains: 250 ppm BHT as inhibitorDensity: 0.889 g/mL at 25°C(lit.)Expl. Lim.: 11.8 %Grade: anhydrousImpurities: ≤0.005% peroxides (as H2O2)MP: −108°C(lit.)Refractive Index: n20/D 1.407(lit.)Vapor Density: 2.5 (vs air)Vapor Pressure: 114 mmHg ( 15°C)

Additional Information

SKU 5279936
UOM Each
UNSPSC 12191501
Manufacturer Part Number 186562-18L
CAS Number 109-99-9
HS Code 2932110000
UN Number UN 2924
Proper Shipping Name Tetrahydrofura
Packaging Group PG II
DG or HZ DG
Hazardous Class 3
Label
Molecular Formula C4H8O
EC Number 203-726-8
HIN 33
Hazard Statement H225-H302-H319-H335-H336-H351
Precautionary Statements P201-P303+P361+P353-P405-P501a-P210-P280-P301+P312+P330-P305+P351+P338-P370+P378-P403+P235
Risk Statements 36/37/38-36/37-19-11-40
GHS GHS02,GHS07,GHS08
GHS (Pictogram)
Safety Statements 26-36-33-29-16-46-37-13
Hazard Code Xi,F,X
Signal Word Danger